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Posted: December 30th, 2024
kinetics (physical chemistry)
Question description
Given two expressions for the rate constant for the reacion C4H9O + NO yields products.1) k = 7.8 x 10^-12 exp(+2.85 kJ/mol) cm^3/mol2) k = 4.2 x 10^-11 (T/200)^-1.27 cm^3/molDo these two expressions yield significantly different rate constants from each other in the temperature range from 200-400K? What if anything is the physical significance of any part of either expression?I don't quite know what to do. Of course they are significantly different. You can tell that without doing anything. But I don't understand the expressions. I think they have something to do with Gibbs free energy and/or enthalpy but I'm just guessing about this. Can you help?
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