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Posted: December 10th, 2019
Question description
In a certain chemical cross-linking reaction involving
a monomer that can react at three sites,
the degree of the reaction, f obeys
the second order rate law.df/dt = k (1-f)^2Where the rate
constant, k has the value 4 x 10-4 s-1. Use the Flory-Stockmayer
to calculate.
a. the time at which
the gel point is reached
b. the time after which
three quarters of the monomers have been polymerized.
c. the time after which
three-quarters of the monomers form part of the infinite network.
This Question comes from Ch. 6 of the following book.http://www.fulviofrisone.com/attachments/article/403/soft_condensed_matter_jones_oup_2002.pdf
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